Regioselective synthesis and molecular structure of the first derivative of praseodymium-containing metallofullerenes.
نویسندگان
چکیده
Regioselective cycloaddition of adamantylidene carbene to Pr@C(2v)(9)-C82 affords the first derivative of praseodymium-containing metallofullerenes. Single-crystal X-ray crystallographic data in combination with theoretical studies demonstrate that the addition is dictated by the single metal ion encapsulated inside the fullerene cage.
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عنوان ژورنال:
- Chemical communications
دوره 50 69 شماره
صفحات -
تاریخ انتشار 2014